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ChemInform Abstract: Mechanistic Roles of Metal-to-Ligand Charge-Transfer Excited States in Organometallic Photochemistry

✍ Scribed by Antonin Vlcek Jr.

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures