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ChemInform Abstract: Metal—CO Photodissociation in Transition Metal Complexes: The Role of Ligand-Field and Charge-Transfer Excited States in the Photochemical Dissociation of Metal—Ligand Bonds

✍ Scribed by E. J. Baerends; A. Rosa

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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trans–cis Photoisomerization of the Styrylpyridine Ligand in [Re(CO)3(2,2′-bipyridine)(t-4-styrylpyridine)]+: Role of the Metal-to-Ligand Charge-Transfer Excited States
✍ Julien Bossert; Chantal Daniel 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB

## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures