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Metal—Molecule charge-transfer excitations on silver films

✍ Scribed by D. Schmeisser; J.E. Demuth; Ph. Avouris

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
267 KB
Volume
87
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rcccivcd 15 Ocrobcr 198 I, I" ilml iornl7 January 1982 Ekc~ron cnerg loss spccw oiCO.02. C?H~,ald CsHjN ddsorbed on srlvcr fdms evaporated at 7-O E show rn add!-Iron to tbr inrram!Aecular transwons. new bands beluccn 1 and 1 eV. Thcsc are Idcnrfied 3s metal-molecule clwge-IraNicr evararions loczlizcd at s~tcsof mrcroscoplc roushntis and occur for molecules that show surfacc<nhanced Raman srxttermg under similar condrllons

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The method for calculating solvent shifts on metal to ligand charge transfer (MLCT) and other electronic absorption bands involving charge transfer (e.g. ligand to metal and organic charge transfer) developed by Zeng, Hush and Reimers, henceforth named ZHR-SS, is reviewed. Also included are simple m