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Solvent effect for ruthenium porphyrin

✍ Scribed by Izumi Iwakura; Atshi Yabushita; Takayoshi Kobayashi

Book ID
107363684
Publisher
Science in China Press (SCP)
Year
2010
Tongue
English
Weight
872 KB
Volume
53
Category
Article
ISSN
1672-1799

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πŸ“œ SIMILAR VOLUMES

Solvent effect on ruthenium catalyzed di
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The effect of different solvents on flash dihydroxylation is compared and for the first time, the replacement of ethyl acetate with acetone was shown to give a successful, cata/ytic cisdihydroxylation of the alkene moiety in cholesteryl acetate and the ruthenium catalytic cycle could be maintained b

Decomposition of cyclohexyl hydroperoxid
Decomposition of cyclohexyl hydroperoxide catalysed by ruthenium porphyrins. Hydroxylation of the solvent cyclohexane
✍ C.B. Hansen; F.P.W. Agterberg; A.M.C. van Eijndhoven; W. Drenth πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 878 KB

Ruthenium tetraarylporphyrins have been used as catalysts in the decomposition of cyclohexyl hydroperoxide. During this decomposition reaction the ruthenium tetraarylporphyrin/cyclohexyl hydroperoxide system is capable of hydroxylating the solvent, i.e. cyclohexane or cyclopentane. A proposal for th