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Decomposition of cyclohexyl hydroperoxide catalysed by ruthenium porphyrins. Hydroxylation of the solvent cyclohexane

✍ Scribed by C.B. Hansen; F.P.W. Agterberg; A.M.C. van Eijndhoven; W. Drenth

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
878 KB
Volume
102
Category
Article
ISSN
1381-1169

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✦ Synopsis

Ruthenium tetraarylporphyrins have been used as catalysts in the decomposition of cyclohexyl hydroperoxide. During this decomposition reaction the ruthenium tetraarylporphyrin/cyclohexyl hydroperoxide system is capable of hydroxylating the solvent, i.e. cyclohexane or cyclopentane. A proposal for the mechanism is presented. The hydroxylating capacity of various ruthenium complexes is discussed.

πŸ“œ SIMILAR VOLUMES

Mechanistic study of decomposition of cy
Mechanistic study of decomposition of cyclohexyl hydroperoxide catalysed by manganese(III) tetraarylporphyrins
✍ Carola B. Hansen; Guido Mul; Roland B. J. Tabor; Wiendelt Drenth πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 619 KB

## Abstract The reaction between manganese(III) tetraarylporphyrins and cyclohexyl hydroperoxide has been investigated. Since pyridine increases the decomposition rate of cyclohexyl hydroperoxide, all experiments were performed in the presence of pyridine. Experiments with 2,6‐di‐tert‐butylpyridine