Ruthenium tetraarylporphyrins have been used as catalysts in the decomposition of cyclohexyl hydroperoxide. During this decomposition reaction the ruthenium tetraarylporphyrin/cyclohexyl hydroperoxide system is capable of hydroxylating the solvent, i.e. cyclohexane or cyclopentane. A proposal for th
Metalloporphyrin-Catalyzed Hydroxylation of Cyclohexane by Alkyl Hydroperoxides: Pronounced Efficiency of Iron-Porphyrins
✍ Scribed by Dr. Daniel Mansuy; Dr. Jean-François Bartoli; Prof. Dr. Jean-Claude Chottard; Dr. Marc Lange
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 275 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0044-8249
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The catalytic activities of aryl-chlorinated iron tetraarylporphyrins with and without chloro substituents at the I~-pyrrole positions--third and second generation catalysts, respectively--were compared for the hydroxylation of ethylbenzene and cyclohexane by iodosylbenzene. The results reveal that
The non-heme iron complex, Fe(TPAA = tris-[N-(2-pyridylmethyl)-2-aminoethyl]amine)(ClO 4 ) 2 , is a bad catalyst for the epoxidation of alkenes such as cyclooctene, cyclohexene and cis-stilbene and for the hydroxylation of alkanes such as adamantane by H 2 O 2 , when compared to the iron porphyrin F