Hydroxylation of simple alkanes by iodosylbenzene is catalyzed more efficiently by second than by third generation iron(III) porphyrins
✍ Scribed by Zeev Gross; Liliya Simkhovich
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 261 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The catalytic activities of aryl-chlorinated iron tetraarylporphyrins with and without chloro substituents at the I~-pyrrole positions--third and second generation catalysts, respectively--were compared for the hydroxylation of ethylbenzene and cyclohexane by iodosylbenzene. The results reveal that despite the somewhat larger stability of the former complexes to the oxidative reaction conditions, they are less efficient catalysts than the corresponding unsubstituted complexes, which catalyze the transformation of the alkanes into their oxygenated products with almost 80% yield at more than 10% conversion. It is proposed that for the third generation catalyst the extremely short life time of the most potent intermediate is responsible for the relatively low efficiency in catalysis.