Ruthenium tetraarylporphyrins have been used as catalysts in the decomposition of cyclohexyl hydroperoxide. During this decomposition reaction the ruthenium tetraarylporphyrin/cyclohexyl hydroperoxide system is capable of hydroxylating the solvent, i.e. cyclohexane or cyclopentane. A proposal for th
Anchored manganese and ruthenium porphyrins as catalysts in the decomposition of cyclohexyl hydroperoxide
β Scribed by C.B. Hansen; G.J. Hoogers; W. Drenth
- Publisher
- Elsevier Science
- Year
- 1993
- Weight
- 755 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
The binuclear MnlV-Mn Iv manganese complex lcatalyzes the periodic acid oxidation of sulfides to sulfones under mild conditions. The reaction was found to be highly selective giving almost quantitative yields of the sulfones even in the presence other easily oxidized groups. Only amines were found t
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