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Binuclear manganese complexes as catalysts in the selective and efficient oxidation of sulfides to sulfones

✍ Scribed by Derek H.R. Barton; Wenge Li; Jason A. Smith

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 194 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01518-4

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✦ Synopsis

The binuclear MnlV-Mn Iv manganese complex lcatalyzes the periodic acid oxidation of sulfides to sulfones under mild conditions. The reaction was found to be highly selective giving almost quantitative yields of the sulfones even in the presence other easily oxidized groups. Only amines were found to hinder the reaction.

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