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Solvent Effects on Rate Constants for One-Electron Oxidation of Porphyrins

โœ Scribed by Marguet, S.; Hapiot, P.; Neta, P.


Book ID
118173244
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
780 KB
Volume
98
Category
Article
ISSN
0022-3654

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Rate constants for one-electron oxidatio
โœ Robert E. HUIE; P. NETA ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 336 KB ๐Ÿ‘ 1 views

Rate constants for one-electron oxidation by the methylperoxyl radicals (CH302, HOCHzO;, -O2CCHz0;, and CClsO;) in aqueous solutions have been measured by pulse radiolysis and found to be in the range of 3 x lo5 to 6 x lo8 M-' sK1 for compounds with redox potentials between 0.6 and 0.1 V. Substituti