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Solid phase synthesis of depsides and depsipeptides

✍ Scribed by Oliver Kuisle; Emilio Quiñoá; Ricardo Riguera

Book ID
108387316
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
244 KB
Volume
40
Category
Article
ISSN
0040-4039

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Viscosin, a cyclic depsipeptide (containing a peptide lactone) has been prepared by solid-phase chemistry using an Fmoc-protocol starting with an acid sensitive resin. Cyclization with the activating agent BOP-Cl gave a product which was indistinguishable from natural viscosin thereby supporting the