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Solid-Phase Synthesis of 3,4-Dihydro-1 H -pyrimidine-2-ones Using Sodium Benzenesulfinate as a Traceless Linker

✍ Scribed by Li, Weiwei; Lam, Yulin

Book ID: 120002023
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 121 KB
Volume: 7
Category: Article
ISSN: 1520-4766
DOI: 10.1021/cc0500295

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The synthesis of 3,4-dihydro-2(IH)-quinolinones has been accomplished through the rearrangement of ~lactam intermediates on the solid-phase. The ~-laetam intermediates were constructed through [2+2] cycloadditions between ketenes and imines on the solid-phase. A library of 4,140 dihydroquinolinones