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Singlet oxygenation of cycloocta-1,3,5-triene formation of (4.2.2.)- and (2.2.2.)- cycloadducts

✍ Scribed by Waldemar Adam; Ihsan Erden

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
46 KB
Volume
21
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Singlet oxygenation of cycloocta-1,3,5-t
Singlet oxygenation of cycloocta-1,3,5-triene: Formation of (4.2.2)- and (2.2.2)- cycloadducts.
✍ Waldemar Adam; Ihsan Erden πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 216 KB

Photosensitized singlet oxygenation of 1,3,5-cyclooctatriene affords the (4.2.2)-and (2.2.2)-type endoperoxides, which were reduced with diimide, thermally isomerized, and deoxygenated with triphenylphosphine. Cycloocta-1,3,5-triene (k) is a versatile substrate for cycloaddition in view of its dive