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Photolysis of Bicyclo[4,2,0]octa-2,4-diene, Cycloocta-1,3,5-triene and Cycloocta-1,3,6-triene

✍ Scribed by Dr. W. R. Roth; Dipl.-Chem. B. Peltzer

Publisher
John Wiley and Sons
Year
1964
Tongue
English
Weight
209 KB
Volume
3
Category
Article
ISSN
0044-8249

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Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres