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A Degenerate Rearrangement of cis-Bicyclo [6.1.0 ]nona-2,4,6-triene

✍ Scribed by Dr. Frank Gerrit Klärner


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
244 KB
Volume
11
Category
Article
ISSN
0044-8249

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Reaction of cis-Bicyclo[6.1.0]nona-2,4,6
✍ Dr. Gernot Boche; Dipl.-Chem. Heinrich Weber; Jürgen Benz 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB 👁 1 views

Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres