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Zur Reaktion von cis-Bicyclo[6.1.0]nona-2,4,6-trien mit Tetracyanäthylen

✍ Scribed by Dr. Gernot Boche; Heinrich Weber; Jürgen Benz

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
215 KB
Volume
86
Category
Article
ISSN
0044-8249

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Reaction of cis-Bicyclo[6.1.0]nona-2,4,6
Reaction of cis-Bicyclo[6.1.0]nona-2,4,6-triene with Tetracyanoethylene
✍ Dr. Gernot Boche; Dipl.-Chem. Heinrich Weber; Jürgen Benz 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB

Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres