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[4 + 2]-Cycloaddition of Singlet Oxygen and Phenyltriazolinedione with Bicyclo[6.1.0]nona-2,4,6-triene and Derivatives

✍ Scribed by Adam, Waldemar ;Cueto, Omar ;De Lucchi, Ottorino


Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
467 KB
Volume
115
Category
Article
ISSN
0009-2940

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Reaction of cis-Bicyclo[6.1.0]nona-2,4,6
✍ Dr. Gernot Boche; Dipl.-Chem. Heinrich Weber; JΓΌrgen Benz πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 238 KB πŸ‘ 1 views

Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres