[π2+π2] Cycloadditions of 4-Phenyl-4H-1,2,4-triazole-3,5-dione and Singlet Oxygen to Homofuran
✍ Scribed by Prof. Dr. Waldemar Adam; Dr. Axel Griesbeck; Prof. Dr. Frank-Gerrit Klärner; Dipl.-Chem. Dietmar Schröer
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 266 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0044-8249
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and 3-aminopyrazole and 3-amino-1,2,4-triazole provide convenient access to biologically relevant 3H-imidazo[1,2-b]pyrazoles and a 5H-imidazo[2,1-c][1,2,4]triazole.
Synthesis of 3
A series of 4-(alkylidene/arylidene)amino-5-(2-furanyl)-2.4-dihydro-3H-I .2.4-triazolc-3-1hiones (2) and 6-aryl-3-(2-furanyl)-7H-12.4-triazolo[3,4-b]( 1.3.41 thiadiazines (3) werc synthesized. The configuration of 2g was assigned on che basis of 'H-NMR data. Of the new derivatives tesced. only 2b. 2