A recently published paper in which the inner-and outer-sphere contributions in redos reactions are compared is incorrect-If one uses the experimental values for the force constants, rather than those calculated from the Urey-Bradley method, one tindsRhmer= 1.6 Rout, where R represents the reorganiz
Single vs double bridging in inner-sphere electron transfer reactions
β Scribed by Soontaree Benjarvongkulchai; Roderick D. Cannon
- Book ID
- 108428535
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 502 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0277-5387
No coin nor oath required. For personal study only.
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## Equations and interpretations in the Khan-Bock& Comment are the same as in the author's paper cxcpt for the valid objection to the computation of literature values of force constants. The argument that inner-sphere reorganization energies are dominant is rather pointless since the opposite view
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