✦ LIBER ✦

Contribution of inner-sphere reorganization in electron-transfer reaction in solution

✍ Scribed by Shahed U.M. Khan; John O'M. Bockris

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 343 KB
Volume: 99
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80274-7

No coin nor oath required. For personal study only.

✦ Synopsis

A recently published paper in which the inner-and outer-sphere contributions in redos reactions are compared is incorrect-If one uses the experimental values for the force constants, rather than those calculated from the Urey-Bradley method, one tindsRhmer= 1.6 Rout, where R represents the reorganization ener=T.

📜 SIMILAR VOLUMES

Reply to “contribution of inner-sphere r

Reply to “contribution of inner-sphere reorganization in electron transfer reaction in solution” by S.U.M. Khan and J.O'M. Bockris

✍ Paul Delahay 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 129 KB

## Equations and interpretations in the Khan-Bock& Comment are the same as in the author's paper cxcpt for the valid objection to the computation of literature values of force constants. The argument that inner-sphere reorganization energies are dominant is rather pointless since the opposite view

An inner-sphere reorganization model of

An inner-sphere reorganization model of hetero-exchange electron transfer reaction of diatomic reactants

✍ Yuxiang Bu; Xinyu Song; Conghao Deng 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 472 KB

An accurate theoretical scheme for obtaining directly the inner-sphere reorganization energies of the hetero-exchange electron transfer reactions from ionization potentials and electron affinities is first reported in this paper. Ionization potentials and electron affinities are alternatively obtain

Anomalous reorganization free energies i

Anomalous reorganization free energies in optical electron transfer in solution

✍ Paul Delahay 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 456 KB

Dynamics of inner- and outer-sphere elec

Dynamics of inner- and outer-sphere electron transfer in a polar solvent

✍ Yuri Dakhnovskii 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 562 KB

Monte Carlo simulation study on reorgani

Monte Carlo simulation study on reorganization energy of electron-transfer reactions in polar solution

✍ Yoshitaka Enomoto; Toshiaki Kakitani; Akira Yoshimori; Yasuyo Hatano; Minoru Sai 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 463 KB

The reorganization energy of electron-transfer reactions as a function of the distance between donor and acceptor molecules is calculated by Monte Carlo simulation. It is found that the reorganization energy of charge-separation reactions is appreciably different from that of charge-recombination re

Ab initio calculation of inner-sphere re

Ab initio calculation of inner-sphere reorganization energy for the Fe2+ (H2O)6/Fe3+ (H2O)6 electron transfer system

✍ Yuxiang Bu; Shuxiang Liu; Xinyu Song 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 460 KB

Two new models, and application of the ab initio MO method, for computing the inner-sphere reorganization energy (RE) of the hydrated ions participating in electron transfer reactions in solution and at electrodes are presented. The inner-sphere RE was calculated for the low-lying state ( ST0/6A,,)