A recently published paper in which the inner-and outer-sphere contributions in redos reactions are compared is incorrect-If one uses the experimental values for the force constants, rather than those calculated from the Urey-Bradley method, one tindsRhmer= 1.6 Rout, where R represents the reorganiz
Anomalous reorganization free energies in optical electron transfer in solution
โ Scribed by Paul Delahay
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 456 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0009-2614
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The reorganization energy of electron-transfer reactions as a function of the distance between donor and acceptor molecules is calculated by Monte Carlo simulation. It is found that the reorganization energy of charge-separation reactions is appreciably different from that of charge-recombination re