Outer-shell-reorganization energy for electron-transfer reactions in reverse micelles
β Scribed by Massimo Dilonardo; Marco Maestro
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 368 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The reorganization energy of electron-transfer reactions as a function of the distance between donor and acceptor molecules is calculated by Monte Carlo simulation. It is found that the reorganization energy of charge-separation reactions is appreciably different from that of charge-recombination re
The radical yield in the electron-transfer reaction between thionine triplet and aniline in reversed micelles is increased by an external magnetic field. The saturation value of the effect amounts to 85% (18 kG) and the B1/2 value is 300 G. The magnetic-field effect is discussed on the basis of the
## Abstract Recent experimental data concerning the rate constants and their free energy of the outer sphere electronβtransfer reactions, as catalyzed by noncoordinated pyridine derivatives in aqueous solution, are examined for possible correlation. For the electron transfer reactions between V or