✦ LIBER ✦

Magnetic-field-enhanced radical yield from triplet electron-transfer reaction in reversed micelles

✍ Scribed by Wolfgang Schlenker; Thomas Ulrich; Ulrich E. Steiner

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 527 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87477-6

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✦ Synopsis

The radical yield in the electron-transfer reaction between thionine triplet and aniline in reversed micelles is increased by an external magnetic field. The saturation value of the effect amounts to 85% (18 kG) and the B1/2 value is 300 G. The magnetic-field effect is discussed on the basis of the radical-pair mechanism with a quantitative consideration of the hyperfmeinduced spin motion.

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