✦ LIBER ✦

The reorganization energies in one-electron oxidation of ferrous complexes in aqueous solution

✍ Scribed by Kaori Ono; Iwao Watanabe; Shigero Ikeda

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 313 KB
Volume: 128
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80341-4

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✦ Synopsis

The photoelectron emission method was used to determine the reorganization free energy of nuclear coordinates in one-electron oxidation reactions. The experimental results for eight ferrous complexes, some of which have large organic ligands, in aqueous solution are in excellent agreement with the theoretical ones.

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