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The aerial oxidation of trivalent chromium in aqueous solution

✍ Scribed by Nyholm, R. S.


Publisher
Wiley (John Wiley & Sons)
Year
1947
Weight
390 KB
Volume
66
Category
Article
ISSN
0368-4075

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✦ Synopsis


Abstract

The oxidation of trivalent chromium in aqueous solution using atmospheric oxygen has been studied. Thermodynamically it has been shown that the oxidation is feasible at pH values greater than 4. In practice the oxidation could be made to proceed only in very alkaline solution with the chromium present presumably as the chromitc ion; also the presence of manganese ion as catalyst was essential. Quantitative oxidation of the chromium could not be achieved as partial precipitation of basic chromium salts occurred on the catalyst.


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