✦ LIBER ✦

Reply to “contribution of inner-sphere reorganization in electron transfer reaction in solution” by S.U.M. Khan and J.O'M. Bockris

✍ Scribed by Paul Delahay

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 129 KB
Volume: 99
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80275-9

No coin nor oath required. For personal study only.

✦ Synopsis

Equations and interpretations in the Khan-Bock&

Comment are the same as in the author's paper cxcpt for the valid objection to the computation of literature values of force constants. The argument that inner-sphere reorganization energies are dominant is rather pointless since the opposite view is equally supported by experiment. The Khan-Bockris force con-

📜 SIMILAR VOLUMES

Contribution of inner-sphere reorganizat

Contribution of inner-sphere reorganization in electron-transfer reaction in solution

✍ Shahed U.M. Khan; John O'M. Bockris 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 343 KB

A recently published paper in which the inner-and outer-sphere contributions in redos reactions are compared is incorrect-If one uses the experimental values for the force constants, rather than those calculated from the Urey-Bradley method, one tindsRhmer= 1.6 Rout, where R represents the reorganiz