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An inner-sphere reorganization model of hetero-exchange electron transfer reaction of diatomic reactants

✍ Scribed by Yuxiang Bu; Xinyu Song; Conghao Deng

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
472 KB
Volume
250
Category
Article
ISSN
0009-2614

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✦ Synopsis

An accurate theoretical scheme for obtaining directly the inner-sphere reorganization energies of the hetero-exchange electron transfer reactions from ionization potentials and electron affinities is first reported in this paper. Ionization potentials and electron affinities are alternatively obtained from the Rydberg spectroscopic data via a numerical procedure for some diatomic molecules. The inner-sphere reorganization energy values are calculated for the hetero-exchange electron transfer reactions (AB + CD+~ AB++ CD) of diatomic molecules and are compared with those from other approximate methods.

📜 SIMILAR VOLUMES

Contribution of inner-sphere reorganizat
Contribution of inner-sphere reorganization in electron-transfer reaction in solution
✍ Shahed U.M. Khan; John O'M. Bockris 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 343 KB

A recently published paper in which the inner-and outer-sphere contributions in redos reactions are compared is incorrect-If one uses the experimental values for the force constants, rather than those calculated from the Urey-Bradley method, one tindsRhmer= 1.6 Rout, where R represents the reorganiz

Reply to “contribution of inner-sphere r
Reply to “contribution of inner-sphere reorganization in electron transfer reaction in solution” by S.U.M. Khan and J.O'M. Bockris
✍ Paul Delahay 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 129 KB

## Equations and interpretations in the Khan-Bock& Comment are the same as in the author's paper cxcpt for the valid objection to the computation of literature values of force constants. The argument that inner-sphere reorganization energies are dominant is rather pointless since the opposite view