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Stereoselectivity in Reactions of Metal Complexes. Part X. Kinetics and stereoselectivity of the inner-sphere electron-transfer reaction between [Co(bamap)H2O]+ (bamap = 2,6-bis(3-carboxy-1,2-dimethyl-2-azapropyl)pyridine) and optically active iron(II) complexes

✍ Scribed by Klaus Bernauer; Philippe Pousaz; Joelle Porret; André Jeanguenat

Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
627 KB
Volume
71
Category
Article
ISSN
0018-019X

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✦ Synopsis

Kinetics and Stereoselectivity of the

Inner-sphere Electron-Transfer Reaction between [Co(bamap)H,Or (bamap = 2,6-Bis(3-carboxy-l,2-dimethyl-2-azapropyl)pyridine) and Optically Active Iron(I1) Complexes

📜 SIMILAR VOLUMES

Stereoselectivity in Reactions of Metal
Stereoselectivity in Reactions of Metal Complexes. Part XVII. Synthesis of three new optically active triamines: 2,6-Bis{[(2S)-2-(hydroxymethyl)pyrrolidin-1-yl]methyl}pyridine, 2,6-bis{[(2S)-2-(methoxymethyl)pyrrolidin-1-yl]methyl}pyridine, and 2,6-bis{{(2S)-2-[(benzyloxy)methyl]pyrrolidin-1-yl}methyl}pyridine. X-ray structure and equilibrium behaviour of their copper(II) complexes
✍ Klaus Bernauer; Thierry Chuard; Helen Stoeckli-Evans 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 697 KB

## Abstract The three new optically active triamines derived from 2,6‐bis(aminomethyl)pyridine, __i.e.__ 2,6‐bis{[(2__S__)‐2‐(hydroxymethyl)pyrrolidin‐1‐yl]methyl}pyridine (3a), 2,6‐bis{[(2__S__)‐2‐(methoxymethyl)pyrrolidin‐1‐yl]methyl}‐pyridine (3b), and 2,6‐bis{{(2__S__)‐2‐[(benzyloxy)methyl]pyrr