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Si94– Anions in Solution – Structures of the Solvates Rb4Si9·4.75NH3 and [Rb(18-crown-6)]Rb3Si9·4NH3, and Chemical Bonding in Si94–

✍ Scribed by Stefanie Joseph; Christof Suchentrunk; Florian Kraus; Nikolaus Korber

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 834 KB
Volume: 2009
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200900230

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Chemical Bond in the Cyclic Anions P64−

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The bonding in the As 6 4À ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 •6 NH 3 . Theoretical analysis of the related P 6 4À ion indicates an unusual P¼P bond which contains major contributions from the lone pairs. Outside a highl

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