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Chemical Bond in the Cyclic Anions P64- and As64-: Synthesis, Crystal Structure, and Electron Localization Function of {Rb([18]crown-6) }2Rb2As6×6NH3.

✍ Scribed by Florian Kraus; Tobias Hanauer; Nikolaus Korber

Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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Chemical Bond in the Cyclic Anions P64−
Chemical Bond in the Cyclic Anions P64− and As64−: Synthesis, Crystal Structure, and Electron Localization Function of {Rb[18]crown-6)}2Rb2As6⋅6 NH3
✍ Florian Kraus; Tobias Hanauer; Nikolaus Korber 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 451 KB 👁 2 views

The bonding in the As 6 4À ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 •6 NH 3 . Theoretical analysis of the related P 6 4À ion indicates an unusual P¼P bond which contains major contributions from the lone pairs. Outside a highl

Dimers of Heptapnictide Anions: As144- a
Dimers of Heptapnictide Anions: As144- and P144- in the Crystal Structures of [Rb(18-Crown-6)]4As14×6NH3 and [Li(NH3)4] 4P14×NH3.
✍ Tobias Hanauer; Juergen C. Aschenbrenner; Nikolaus Korber 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 10 KB

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