Dimers of Heptapnictide Anions: As144- and P144- in the Crystal Structures of [Rb(18-Crown-6)]4As14×6NH3 and [Li(NH3)4] 4P14×NH3.
✍ Scribed by Tobias Hanauer; Juergen C. Aschenbrenner; Nikolaus Korber
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 10 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The bonding in the As 6 4À ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 •6 NH 3 . Theoretical analysis of the related P 6 4À ion indicates an unusual P¼P bond which contains major contributions from the lone pairs. Outside a highl