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Selective reduction of organic compounds with indium hydride reagents

✍ Scribed by Masafumi Yamada; Koji Tanaka; Shuki Araki; Yasuo Butsugan


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
185 KB
Volume
36
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Diastereoselective reduction of acyclic
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Hydroxyketones and diketones have been reduced with lithium indium hydride to give meso-diols selectively, cΒ’-Hydroxyketones and 0c-diketones are reduced to meso-l,2-diols with high diastereoselectivities, whereas the selectivities of ~hydroxyketones and [~diketones are less satisfactory.

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Dichloroindium hydride (Cl 2 InH), which was generated in situ by transmetallation between tributyltin hydride and indium trichloride, acted as a novel radical initiator for the reduction of organic halides with tributyltin hydride. The reaction was revealed to proceed through a radical process unde

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v