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Indium hydride: a novel radical initiator in the reduction of organic halides with tributyltin hydride

✍ Scribed by Katsuyuki Inoue; Akemi Sawada; Ikuya Shibata; Akio Baba

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 60 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00816-4

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✦ Synopsis

Dichloroindium hydride (Cl 2 InH), which was generated in situ by transmetallation between tributyltin hydride and indium trichloride, acted as a novel radical initiator for the reduction of organic halides with tributyltin hydride. The reaction was revealed to proceed through a radical process under non-oxygen conditions at room temperature, and to be applicable to intramolecular radical cyclizations.

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