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Selective reductions with stable indium trihydride reagents

✍ Scribed by Colin D Abernethy; Marcus L Cole; Aaron J Davies; Cameron Jones


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
123 KB
Volume
41
Category
Article
ISSN
0040-4039

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Hydroxyketones and diketones have been reduced with lithium indium hydride to give meso-diols selectively, cΒ’-Hydroxyketones and 0c-diketones are reduced to meso-l,2-diols with high diastereoselectivities, whereas the selectivities of ~hydroxyketones and [~diketones are less satisfactory.