Selective oxidation of alcohols in a continuous multifunctional reactor: Ruthenium oxide catalysed oxidation of benzyl alcohol
โ Scribed by Dmitry V. Bavykin; Alexei A. Lapkin; Stan T. Kolaczkowski; Pawel K. Plucinski
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 294 KB
- Volume
- 288
- Category
- Article
- ISSN
- 0926-860X
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๐ SIMILAR VOLUMES
Allylic and benzylic alcohols are oxidised to the corresponding carbonyl compounds using tert-butyl hydroperoxide, preferably in stoichiometric amounts, and dirhodium(II) tetraacetate as catalyst (1 mol%) in dichloromethane at ambient temperature.
## Abstract A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using __in situ__ generated iron chloride complexes [Fe(**L3**)~2~Cl~n~] [n=0โ1, **L3** =6โ(__N__โphenylbenzimidazoyl)โ2โpyridinecarboxylic acid], aldehydes and keto