𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dirhodium(II) carboxylate-catalysed oxidation of allylic and benzylic alcohols

✍ Scribed by Christopher J Moody; Francine N Palmer

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
64 KB
Volume
43
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Allylic and benzylic alcohols are oxidised to the corresponding carbonyl compounds using tert-butyl hydroperoxide, preferably in stoichiometric amounts, and dirhodium(II) tetraacetate as catalyst (1 mol%) in dichloromethane at ambient temperature.

📜 SIMILAR VOLUMES

ChemInform Abstract: Dirhodium(II) Carbo
ChemInform Abstract: Dirhodium(II) Carboxylate-Catalyzed Oxidation of Allylic and Benzylic Alcohols.
✍ Christopher J. Moody; Francine N. Palmer 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Selective Iron-Catalyzed Oxidation of Be
Selective Iron-Catalyzed Oxidation of Benzylic and Allylic Alcohols
✍ Benoît Join; Konstanze Möller; Carolin Ziebart; Kristin Schröder; Dirk Gördes; K 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 434 KB 👁 2 views

## Abstract A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using __in situ__ generated iron chloride complexes [Fe(**L3**)~2~Cl~n~] [n=0–1, **L3** =6‐(__N__‐phenylbenzimidazoyl)‐2‐pyridinecarboxylic acid], aldehydes and keto

TEMPO-Copper(II) Diimine-Catalysed Oxida
TEMPO-Copper(II) Diimine-Catalysed Oxidation of Benzylic Alcohols in Aqueous Media
✍ Paweł J. Figiel; Markku Leskelä; Timo Repo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 343 KB

## Abstract __In situ__ generated copper(II)‐diimine complexes combined with TEMPO (2,2,6,6‐tetramethylpiperidinyl‐1‐oxyl radical) were studied in the oxidation of benzylic alcohols, the focus being on enviromentally benign reaction conditions. In this respect, reactions were studied in aqueous alk

ChemInform Abstract: Sodium Bismuthate M
ChemInform Abstract: Sodium Bismuthate Mediated Oxidation of Allylic and Benzylic Alcohols.
✍ Bimal K. Banik; Anjan Ghatak; M. S. Venkatraman; Frederick F. Becker 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Effective chromium-mediated oxidation of
Effective chromium-mediated oxidation of allylic and benzylic alcohols by sodium percarbonate
✍ Jacques Muzart; Abdelaziz N'Ait Ajjou; Samia Ait-Mohand 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 205 KB

High sektivity to the corresponding ketones and atdehydea has heen obsavcd for the title readion when pafommi in 1.2-dichlaoerbane at 80°C ia the presence of catalytic amounts of pyridinium dicluomate and Adogen 464. The oxidaticn~ of anactivated alcohols was leas efkimt under these conditions. The