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Selective Iron-Catalyzed Oxidation of Benzylic and Allylic Alcohols

✍ Scribed by Benoît Join; Konstanze Möller; Carolin Ziebart; Kristin Schröder; Dirk Gördes; Kerstin Thurow; Anke Spannenberg; Kathrin Junge; Matthias Beller

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
434 KB
Volume
353
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using in situ generated iron chloride complexes [Fe(L3)~2~Cl~n~] [n=0–1, L3 =6‐(N‐phenylbenzimidazoyl)‐2‐pyridinecarboxylic acid], aldehydes and ketones were obtained in good yield and excellent selectivity after a short reaction time at room temperature.

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