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Ruthenium(III)-catalysed oxidation of secondary alcohols by N-methylmorpholine N-oxide (NMO)

✍ Scribed by K. Vijayasri; J. Rajaram; J.C. Kuriacose

Publisher
Elsevier Science
Year
1987
Weight
796 KB
Volume
39
Category
Article
ISSN
0304-5102

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The kinetics of oxidation of six para-substituted diphenylmethanols (Y-DPM, where Y = H, Cl, Br, NO 2 , CH 3 and OCH 3 ) by sodium N-chlorobenzenesulphonamide [chloramine-B (CAB)] in the presence of HCl and catalysed by RuCl 3 in 30% (v/v) methanol medium was studied at 35 Β°C. The experimental rate