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Ruthenium (III)-Schiff base complex catalyzed oxidation of secondary alcohols by N-methylmorpholine-N-oxide or thallium (III) acetate

โœ Scribed by K. J. Tony; V. Mahadevan; J. Rajaram; C. S. Swamy

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
345 KB
Volume
28
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The Ru[lll) Schiff base complex, 1 Ru[ L)CI,ICI; L = Gis[picolinaldehyde) o-phenylenediimine. catalyzes the oxidation of secondary alcohols by N-methylrnorpholine-N-oxide( NMO) or thal-Iium(lll) acetate as oxidant, Kinetic studies showed the formation of R u ( V ) species as the active intermediate 0 1996 lohn Wiley & Sons, Inc.

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