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Enantioselective Oxidation of Secondary Alcohols Catalyzed by Soluble Chiral Polymeric [N′,N′-Bis(salicylidene)ethane-1,2-diaminato(2—)]manganese(III) ([MnIII(Salen)]) Type Complexes in a Biphasic System.

✍ Scribed by Wei Sun; Xiaomei Wu; Chungu Xia

Publisher
John Wiley and Sons
Year
2007
Weight
29 KB
Volume
38
Category
Article
ISSN
0931-7597

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Abstract

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Enantioselective Oxidation of Secondary
Enantioselective Oxidation of Secondary Alcohols Catalyzed by Soluble Chiral Polymeric [N′,N′-Bis(salicylidene)ethane-1,2-diaminato(2−)]manganese(III) ([MnIII(salen)]) Type Complexes in a Biphasic System
✍ Wei Sun; Xiaomei Wu; Chungu Xia 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 56 KB

## Abstract The polymeric [__N__′,__N__′‐bis(salicylidene)ethane‐1,2‐diaminato(2−)]manganese(III) ([Mn^III^(salen)]) type complexes **1** and **2** were successfully applied to the oxidative kinetic resolution of secondary alcohols. The reaction proceeded readily at room temperature with excellent