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Selective and efficient alcoholyses of allylic, secondary- and tertiary benzylic alcohols in the presence of iron (III)

✍ Scribed by Peyman Salehi; Nasser Iranpoor; Farahnaz Kargar Behbahani

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 240 KB
Volume: 54
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)10350-7

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✦ Synopsis

An efficient and selective method for the conversion ofallylic, secondary-and tertiary benzylic alcohols into their corresponding ethers in the presence of iron(III) as FeCI3 and Fe(C104)3 under solvolytic condition is described. The results obtained from an optically active allylic alcohol show that a carbonium ion is formed during the course of the reaction.

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