On the mechanism of alcoholysis of allylic and benzylic alcohols and of epoxides in the presence of ceric ammonium nitrate
β Scribed by Jean-Marc Chapuzet; Sophie Beauchemin; Benoit Daoust; Jean Lessard
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 243 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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An efficient and selective method for the conversion ofallylic, secondary-and tertiary benzylic alcohols into their corresponding ethers in the presence of iron(III) as FeCI3 and Fe(C104)3 under solvolytic condition is described. The results obtained from an optically active allylic alcohol show tha
## Abstract The reactivity of allyl alcohols of the pinane series and of their epoxides in the presence of montmorillonite clay in intraβ and intermolecular reactions was studied. Mutual transformations of (+)β__trans__βpinocarveol ((+)β**2**) and (β)βmyrtenol ((β)β**3a**) were major reactions of t