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Novel synthesis of tertiary alkyl, secondary and tertiary benzyl, and allyl selenides from the corresponding alcohols

✍ Scribed by M. Clarembeau; A. Krief


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
181 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


We report an efficient synthesis of the title compounds from alcohols and selenols.

The scope and limitations of the new method are disclosed.


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An efficient and selective method for the conversion ofallylic, secondary-and tertiary benzylic alcohols into their corresponding ethers in the presence of iron(III) as FeCI3 and Fe(C104)3 under solvolytic condition is described. The results obtained from an optically active allylic alcohol show tha