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Secondary Metabolites from Fusarium. Two New Modified Trichothecenes from Fusarium sporotrichioides MC-72083

✍ Scribed by Corley, David G.; Rottinghaus, George E.; Tempesta, Michael S.

Book ID
121500121
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
416 KB
Volume
50
Category
Article
ISSN
0163-3864

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New trichothecene mycotoxins of Fusarium
New trichothecene mycotoxins of Fusarium sporotrichioides (MC-72083)
✍ David G Corley; George E Rottinghaus; John K Tracy; Michael S Tempesta πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 230 KB

Isolation and characterization of three new trichothecene mycotoxins from Fusarium sporotrichioides MC-72083 are reported. Structure and n.m.r. assignments were made using COSY, NOESY and INAPT as well as other spectroscopic techniques. The trichothecenes are a growing class of toxic sesquiterpenoid

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## Abstract Sambucinol (**2**) and sambucoin (**4**), two C~15~‐trichothecenes, have been isolated from cultures of __Fusarium sambucinum__. The structures were deduced from spectroscopic data and by X‐ray diffractoin. A hypothetical biogenetic pathway is proposed.