Scope, mechanism and diene inhibition of isomerization of allylic alcohols to saturated ketones catalyzed by ruthenium(II)-cyclopentadienyl complexes
✍ Scribed by Robert C. van der Drift; Marcella Gagliardo; Huub Kooijman; Anthony L. Spek; Elisabeth Bouwman; Eite Drent
- Book ID
- 108187980
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 323 KB
- Volume
- 690
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
## Abstract A dicationic dichloro‐bipyridine‐ruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethyl‐bipyridine‐ruthenium complex shows reverse catalytic activ
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract A Ru(II)—dichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.