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ChemInform Abstract: Highly Efficient Redox Isomerization of Allylic Alcohols and Transfer Hydrogenation of Ketones and Aldehydes Catalyzed by Ruthenium Complexes.

✍ Scribed by Pei Nian Liu; Kun Dong Ju; Chak Po Lau

Publisher
John Wiley and Sons
Year
2011
Weight
63 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A Ru(II)—dichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.

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