Ruthenium-Catalyzed Reduction of Allylic Alcohols: An Efficient Isomerization/Transfer Hydrogenation Tandem Process.
โ Scribed by Victorio Cadierno; Javier Francos; Jose Gimeno; Noel Nebra
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 27 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
## Abstract A dicationic dichloroโbipyridineโruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethylโbipyridineโruthenium complex shows reverse catalytic activ
## Abstract A Ru(II)โdichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.