𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Efficient Isomerization of Allylic Alcohols to Saturated Carbonyl Compounds by Activated Rhodium and Ruthenium Complexes

✍ Scribed by Ramalinga Uma; Maxwell K. Davies; Christophe Crévisy; René Grée


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
230 KB
Volume
2001
Category
Article
ISSN
1434-193X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Highly Efficient Redox Isomerization of
✍ Pei Nian Liu; Kun Dong Ju; Chak Po Lau 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB 👁 2 views

## Abstract A dicationic dichloro‐bipyridine‐ruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethyl‐bipyridine‐ruthenium complex shows reverse catalytic activ

Catalytic Isomerization of Allylic Alcoh
✍ Pascale Crochet; Josefina Díez; Mariano A. Fernández-Zúmel; José Gimeno 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB

## Abstract The water‐soluble complexes [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3n~(OCH~2~CH~2~NMe~3~)~n~}][SbF~6~]~n~ [n=1 (4a), 2 (4b) or 3 (4c)] have been prepared from the neutral precursors [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3‐n~(OCH~2~CH~2~NMe~2~)~n~}] [n=1 (2a), 2 (2b) or 3

Isomerization of Propargylic Alcohols in
✍ Victorio Cadierno; Sergio E. García-Garrido; José Gimeno 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB 👁 1 views

## Abstract The 16‐e^−^ (η^3^‐allyl)‐ruthenium(II) complex [Ru(η^3^‐2‐C~3~H~4~Me)(CO)(dppf)][SbF~6~] is an efficient catalyst for the regioselective isomerization of terminal propargylic alcohols HCCCR^1^R^2^(OH) into α,β‐unsaturated aldehydes R^1^R^2^CCHCHO or ketones R^3^R^4^CC(R^1^)COMe (if R