✦ LIBER ✦

Scalemic 2-Formyl-3-hydroxy[2.2]paracyclophane: A New Auxiliary for Asymmetric Synthesis

✍ Scribed by Dr. Valeria Rozenberg; Dr. Vladimir Kharitonov; Dipl.-Chem. Dimitri Antonov; Dipl.-Chem. Elena Sergeeva; Dipl.-Chem. Andrei Aleshkin; Dr. Nickolai Ikonnikov; Dipl.-Chem. Svetlana Orlova; Prof. Dr. Yuri Belokon'

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 233 KB
Volume: 33
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199400911

No coin nor oath required. For personal study only.

✦ Synopsis

903-919.

[13] The simulations for 1 were performed according to the published procedure [12] with a temperature parameter of 303 K and 2 x lo6 macro steps. Maximum step lengths were 20" ($), 20" ($). 25' (w), and 2.5" (T = C1'-01'-C6), leading to an overall acceptance ratio of 0.48.

📜 SIMILAR VOLUMES

ChemInform Abstract: Planar Chiral Hydro

ChemInform Abstract: Planar Chiral Hydroxy Derivatives of [2.2]Paracyclophane as Auxiliaries for Asymmetric Allylboration.

✍ N. V. Vorontsova; R. P. Zhuravsky; E. V. Sergeeva; E. V. Vorontsov; Z. A. Starik 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 23 KB 👁 1 views

ChemInform Abstract: [2.2]Paracyclophane

ChemInform Abstract: [2.2]Paracyclophane-Derived N-Acyloxazol-2(3H)-one as a Suitable Planar Chiral Auxiliary for the Enantioselective Synthesis of β-Hydroxy Acids.

✍ Francesco Fringuelli; Oriana Piermatti; Ferdinando Pizzo; Renzo Ruzziconi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

ChemInform Abstract: Asymmetric Synthesi

ChemInform Abstract: Asymmetric Synthesis of (R,S)- and (R,R)-4-Hydroxy-5-(α- substituted)-hydroxymethyl(2.2)paracyclophane and Derivatives by Stereoselective Addition to (R)-4-Hydroxy-5-formyl(2.2)paracyclophane and Derivatives.

✍ E. V. SERGEEVA; V. I. ROZENBERG; E. V. VORONTSOV; T. I. DANILOVA; Z. A. STARIKOV 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

ChemInform Abstract: (S)-2-(Dibenzylamin

ChemInform Abstract: (S)-2-(Dibenzylamino)-3-phenylpropanal as a Chiral Auxiliary: A New Strategy for the Asymmetric Synthesis of 2-Substituted Alcohols.

✍ J. CLAYDEN; C. MCCARTHY; J. G. CUMMING 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

1998 alcohols alcohols (acyclic compounds) P 0110 33 -116 (S)-2-(Dibenzylamino)-3-phenylpropanal as a Chiral Auxiliary: A New Strategy for the Asymmetric Synthesis of 2-Substituted Alcohols. -The key steps in the synthesis of the title alcohols are nucleophilic addition to the aldehyde (I), which p

2-Hydroxy-6-nitrobenzaldehyde (Hnb): A G

2-Hydroxy-6-nitrobenzaldehyde (Hnb): A Generic Acyl Transfer Auxiliary for Peptide Synthesis

✍ Les Miranda; W. Meutermans; M. Smythe; P. F. Alewood 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB

## Abstract For Abstract see ChemInform Abstract in Full Text.

The Synthesis of Pseudo-Geminal, Pseudo-

The Synthesis of Pseudo-Geminal, Pseudo-Ortho and Ortho Hydroxy-oxazolinyl[2.2]paracyclophanes for Use as Ligands in Asymmetric Catalysis

✍ Carsten Bolm; Daniel K. Whelligan 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 1 views

## Abstract Synthetic routes to __pseudo‐geminal__, __pseudo‐ortho__ and __ortho__ hydroxy‐oxazolinyl[2.2]paracyclophanes (and the diastereoisomers of each) for use as N,O ligands in asymmetric catalysis have been devised. The substitution pattern was found to have a strong effect on the rate and e