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ChemInform Abstract: Planar Chiral Hydroxy Derivatives of [2.2]Paracyclophane as Auxiliaries for Asymmetric Allylboration.

โœ Scribed by N. V. Vorontsova; R. P. Zhuravsky; E. V. Sergeeva; E. V. Vorontsov; Z. A. Starikova; V. I. Rozenberg


Publisher
John Wiley and Sons
Year
2008
Weight
23 KB
Volume
39
Category
Article
ISSN
0931-7597

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Use of 9-Anthrylcarbinol Derivatives as Chiral Auxiliaries. Part 2. Asymmetric 1,3-Dipolar Cycloaddition. -Treatment of the acrylate (I) with the nitrone (II) leads to cycloadducts of type (III), (IV), and (V) whose composition depends on steric effects. -(CARRIERE, A.; VIRGILI,